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Finding the right chemistry
The good, the bad and the rusty
When recycling’s risky
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When recycling’s risky
Reutilisation schemes for industrial waste have environmental drawbacks, a REC study finds

By Robert Nemeskeri

Aspiring to become the world’s most competitive economy, Europe has recognised the need for better, more complex and integrated resources management. In communal or consumption waste management, utilisation must be improved because most of the waste stream still goes to landfills or incinerators.

Industry was the first to see the potential of waste utilisation. This practice is positive and economically sound when the by-products are free of harmful substances or when they are safely conditioned to remain inert in the environment. Several concerns involved in the reutilisation of waste have been highlighted in a recent study led by the REC. Although familiar to science for more than three decades, the risks to the environment and public health have yet to be properly addressed by policy makers, the study found.

The REC's Business and Environment Programme, in cooperation with the Institute for Prospective Technology Studies of the EU's Joint Research Centre and respected research institutes from Finland and the Netherlands, has developed scenarios for communal and industrial waste management in the new EU member states through 2020.

Results of Hungary’s Ajka coal power plant fly ash analysis
Element Concentration (µg/g)
  COAL A COAL B
Calcium 49,300 52,500
Titanium 566 639
Vanadium 135 188
Chromium 58.5 48.6
Manganese 111 122
Iron 9,690 12,000
Nickel 21.5 31.5
Copper 26.4 27.2
Zinc 21.4 19.6
Arsenic 13.9 14.1
Selenium 7.54 10.8
Brome 7.27 10.4
Rubidium 7.84 7.49
Strontium 571 603
Lead <5.9 <5.9
Uranium 58 58
Source:
OSAN, J. (1996). Environmental cycle analysis of atmospheric solid particles and power plant ashes. PhD thesis, Central Research Institute for Physics of Hungary (KFKI, AEKI)


The study looked at the safety of utilisation regimes for various industrial processes. It examined coal-fired power generation, and the reuse of coal-mining waste rock, ash, slag and flue gas treatment residues. Next, it looked at iron and steel manufacturing and that industry's reuse of slag and desulphurisation residues.

The risks posed by arsenic, cadmium, chromium, lead, mercury, nickel, selenium, uranium, vanadium, and zinc in coal mining waste rocks and power-plant ashes have been pointed out in studies as far back as 1975. Although toxic and potentially toxic elements are generally present in low concentrations in coal, significant mobilisation occurs through leaching due to the very large quantities of coal consumed and waste rocks used in road and railway construction. In the burning of coal, large volumes of highly enriched metallic compounds remain in ashes, which are then incorporated into cement and other building materials because of their bonding and self-hardening properties.

Most industrial researchers tend to focus on studies that benefit the industries in which they work, while clinical health researchers focus on highly specific cause-and-effect relationships. Thus it is imperative that science put the mosaics together and show how these reuse schemes can affect public health, regardless of current economic trends and politics.

Relevant literature reviewed by the REC's team demonstrated strong evidence that these coal industry process residues often contain radioactive elements as well, including uranium, strontium and rubidium. These findings are based on studies reported by researchers all over the world, including a recent one in Hungary using USEPA instrumentation and methodology. Remarkably, the coal lobby has managed to keep this information largely out of the decision makers' view.

Another suspected risky utilisation that the REC's study shed light on is that of residues containing heavy metals from the iron and steel industry. In some EU countries, such residues are mixed into fertilisers, thus polluting the food chain. Since the efficient utilisation of all resources — energy, materials, flora and fauna, and human — is imperative to sustainable development, the utilisation regime of all process residues or wastes has to be carefully designed and monitored in line with strengthening EU environmental and public health criteria. Therefore, thousands of previously developed industrial standards need to be reviewed to satisfy these new criteria.

Robert Nemeskeri is head of the Business and Environment Programme at the REC